ALKANESRadical Halogenation of Alkanes
NUCLEOPHILIC SUBSTITUTIONBimolecular Nucleophilic Substitution (SN2)
of 1° Alkyl Halides
Unimolecular Nucleophilic Substitution (SN1) of 3° Alkyl Halides
Bimolecular Nucleophilic Substitution (SN2) of 1° Alcohols
Unimolecular Nucleophilic Substitution (SN1) of 3° Alcohols
ELIMINATION REACTIONS
Base-Promoted Dehydrohalogenation of 1° Alkyl Halides (E2)
Base-Promoted Dehydrohalogenation of 3° Alkyl Halides (E1)
Acid-promoted Dehydration of 1° Alcohols (E2)
Acid-promoted Dehydration of 3° Alcohols (E1)
ADDITION REACTIONS OF ALKENES AND ALKYNES
Hydrogenation
Addition of HBr to Alkenes
Anti-Markovnikov Addition of HBr to Alkenes
Addition of Bromine (Br2) to Alkenes
 Formation of Halohydrins (Addition of Hal2 and H2O to Alkenes)
Addition of Water to Alkenes
Oxymercuration-Demercuration (Markovnikov Hydration)
Hydroboration-Oxidation (anti-Markovnikov Hydration)
Hydroxylation
Ozonolysis
Epoxidation
Nucleophilic Epoxide Ring-opening
REACTIONS OF DIENES
Additon of HBr
Addition of Halogens (Hal2)
Diels-Alder Cycloaddition
AROMATIC SUBSTITUTION
A General Mechanism for Electrophilic Aromation Substitution
Electrophilic Aromation Halogenation
Electrophilic Aromatic Nitration
Electrophilic Aromatic Sulfonation
Electrophilic Aromatic Alkylation (Freidel-Crafts Alkylation)
Electrophilic Aromatic Acylation (Freidel-Crafts Acylation)
Nucleophilic Aromatic Substitution by Addition-Elimination
Nucleophilic Aromatic Substitution by Elimination-Addition (via
Benzyn)
REACTIONS OF ACIDS AND ACID DERIVATIVES
General Mechanism for Addition-Elimination of Acyl Derivatives
Alcoholysis of Acyl Chlorides
Fischer Esterification
Saponification of Esters
Hydrolysis of Nitriles
Decarboxylation of Carboxylic Acids with a -Carbonyl Group
ADDITION AND ADDITION-ELIMINATION REACTIONS OF ALDEHYDES AND KETONES
General Mechanism for Nucleophilic Addition to Carbonyl Groups
Hydration (addition of Water)
Addition of HCN
Addition of Organometalic Reagents
General Mechanism for Addition-Elimination Reactions of C=O
Wittig Reaction
Ketal Formation (reaction with alcohols)
Reaction with Amines and Amine Derivatives
REACTIONS AT THE -POSITION OF CARBONYL COMPOUNDS
Acid-catalyzed Enol Formation
Base-catalyzed Enol Formation
-Bromination of Aldehydes and Ketones
Acid-catalyzed Aldol Reaction
Base-catalyzed Aldol Reaction
Dehydration of Aldols
Claisen Reaction
Michael Reaction
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ALKANES-E4
SUBSTITUTION-
-
-
-
ELIMINATION
-E12
-E12
-E12
-E12
ADDITION
-
-E12
-
-E12
-E12
-E12
-E4
-
-E12
-E12
-
-E4
DIENES
-E12
-E12
-S3
AROMATIC SUBSTITUTION
-E12
-E12
-E12
-
-E4
-E12
-E4
-E4
ACIDS AND DERIVATIVES
-E3
-E3
-E3
-E3
-
-E4
ALDEHYDES AND KETONES
-
-S2
-S2
-E4
-
-E4
-S2
-S1
ENOLS & ENOLATES
-S2
-S2
-S2
-S3
-S3
-S3
-E3
-E3
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